1、Glass fiber treated with a glycine bridged silane coupling agent
Silane coupling agents play an indispensable role in improving interfacial adhesion of composite materials, but their interaction mechanism is often unclear.
2、Silanes and Siloxanes as Coupling Agents to Glass: A Perspective
This short review examines the application of silane coupling agents to glass surfaces, and how the nature of glass fiber surface affects the application of such coupling agents.
3、Silane Coupling Agents for Fiberglass Composite
Fiberglass for general-purpose applications is treated with a dilute aqueous sizing bath consisting of a combination of ingredients (organic film formers, lubricants, antistats and a silane coupling agent). The silane must be soluble in the aqueous bath at levels of 0.2 to 1 percent.
4、Why Are Silane Coupling Agents Used in Glass
The primary reason for using silane coupling agents in glass-fiber composites is to improve mechanical properties. By facilitating a strong chemical bond between the glass fibers and the polymer matrix, these agents increase the tensile strength and impact resistance of the composite material.
5、Silane Coupling Agent
There are three basic approaches for using silane coupling agents. The silane can be used to treat the surface of the inorganic materials before mixing with the organic resin or it can be added directly to the organic resin or holistic mixing (in organic-inorganic mixture).
Anne Norström: Adsorption of Silane Coupling Agents on Glass Fibre Surfaces
Chemically resistant glass (C-glass) is used as laboratory ware, but is also used for glass fibre manufacture when the need of chemical resistance of the final product is greater than that of E-glass fibres.
Silanes and Siloxanes as Coupling Agents to Glass: A Perspective
This short review examines the application of silane coupling agents to glass surfaces, and how the nature of glass fiber surface affects the application of such coupling agents.
Glass fiber treated with a glycine bridged silane coupling agent
Firstly, glycine bridged silane (GBSilane) was synthesized and the structure was confirmed by FT-IR, 1 H NMR and HRMS. Secondly, with glass fiber treated using GBSilane as a filler, the mechanical properties of glass fiber/PA6 composite materials were studied.
Application of Silane Coupling Agent for Glass Fiber
Silane coupling agents are used in glass fibers for general-purpose reinforced plastics such as automotive, marine, sports equipment, and construction, as well as high-performance applications such as printed circuit boards and aerospace composites.
Molecular investigation on interfacial toughening between silane
Abstract Silane coupling agents (SCAs) are widely used as adhesion promoters to tightly bond glass fiber (GF) and cement matrix (CM) for developing sustainable and high-performance glass fiber-reinforced cementitious (GFRC) composites.
In modern materials science, glass fibers, as a lightweight and high-strength material, are widely used in aerospace, automotive manufacturing, construction, and electronics industries. maximizing the performance of this material has always been a goal pursued by materials scientists and engineers. Silane coupling agents, as critical additives, offer possibilities for achieving this goal through surface modification of glass fibers. This article explores the process, principles, and impact of incorporating silane coupling agents into glass fibers on composite material properties.
1. Basic Concept of Silane Coupling Agents
Silane coupling agents are organic compounds containing silicon atoms, with molecular structures that include reactive groups capable of undergoing chemical reactions with inorganic or organic substances. When silane coupling agents come into contact with the surface of glass fibers, chemisorption occurs. The reactive groups of the silane coupling agents react with hydroxyl groups or other reactive functional groups on the glass fiber surface, forming covalent or ionic bonds. This achieves surface modification of the glass fibers.
2. Process of Incorporating Silane Coupling Agents into Glass Fibers
1. Pretreatment: Before adding silane coupling agents to glass fibers, the fibers must be pretreated. This includes cleaning and drying to remove oils, dust, and other impurities from the glass fiber surface, ensuring its cleanliness.
2. Mixing: Silane coupling agents are mixed with an appropriate solvent (such as ethanol, acetone, etc.) to prepare a solution. The glass fibers are then soaked in the silane coupling agent solution and thoroughly stirred to ensure uniform distribution of the silane coupling agents on the glass fiber surface.
3. Curing: The treated glass fibers are removed and placed in a well-ventilated environment to air dry naturally or cured using equipment like ovens. During curing, the silane coupling agents react with the glass fiber surface to form stable chemical bonds.
3. Principles of Incorporating Silane Coupling Agents into Glass Fibers
After incorporation, silane coupling agents form a thin protective layer on the glass fiber surface. This layer has the following characteristics:
1. Improved Adhesion: The reaction between silane coupling agents and the glass fiber surface generates new chemical bonds, enhancing the adhesion between glass fibers and other materials.
2. Enhanced Mechanical Performance: The addition of silane coupling agents reduces the surface energy of glass fibers, facilitating interactions with other materials and improving the overall mechanical properties of composites.
3. Increased Heat Resistance: Cross-linking reactions between silane coupling agents and the glass fiber surface improve the heat resistance of composites, maintaining stability at high temperatures.
4. Strengthened Corrosion Resistance: The protective layer formed by silane coupling agents prevents corrosion of glass fibers, extending the service life of composites.
4. Impact of Silane Coupling Agents on Composite Material Properties
1. Enhanced Adhesion Strength: By reacting with the glass fiber surface, silane coupling agents improve the adhesion strength between glass fibers and other materials, making composites more reliable.
2. Improved Mechanical Performance: The interaction between glass fibers and other materials is strengthened, enhancing the overall mechanical properties of composites to meet diverse application demands.
3. Increased Heat Resistance: Cross-linking reactions improve the heat resistance of composites, enabling stable performance at higher temperatures.
4. Enhanced Corrosion Resistance: The protective layer formed by silane coupling agents prevents glass fiber corrosion, extending composite lifespan and reducing maintenance costs.
As a novel additive, silane coupling agents hold broad prospects for surface modification of glass fibers. By carefully selecting the type and concentration of silane coupling agents, efficient modification of glass fibers can be achieved, leading to superior composite materials. With advancements in technology and new material development, the applications of silane coupling agents will continue to expand, providing high-quality material solutions for various industries.

